BEGIN:VCALENDAR
VERSION:2.0
PRODID:-//ZContent.net//ZapCalLib 1.0//EN
CALSCALE:GREGORIAN
METHOD:PUBLISH
BEGIN:VEVENT
SUMMARY:Tailoring the Structure, Morphology and Properties of Isodimorphic 
 Random Copolymers by Varying Chemical Structure, Composition and Molecular
  Weight
LOCATION:Chemistry A101
TZID:America/Denver
DTSTART:20250314T160000
UID:2026-04-05-22-10-18@natsci.colostate.edu
DTSTAMP:20260405T221018
Description:About the Semainr:\n\nCombining the properties of parent homopo
 lymers can be accomplished through random copolymerization. However\, when
  the materials are semi-crystalline\, complex behavior may arise. The stru
 cture and properties of semi-crystalline random copolymers (i.e.\, PA-ran-
 PB) depend on their chemical structure. Three general cases have been desc
 ribed in the literature (see Figure below)1: (a) Isomorphism occurs when t
 he chemical structures of PA and PB are very similar\, allowing for total 
 inclusion of both comonomers in the crystal lattice or miscibility in the 
 crystalline state. (b) Conversely\, when the chemical structures differ si
 gnificantly\, the behavior is largely influenced by the exclusion of comon
 omer PB from the crystal lattice of PA and vice-versa\, indicating total e
 xclusion behavior. (c) Isodimorphic copolymers represent the most intrigui
 ng cases\, exhibiting intermediate behavior in which partial inclusion of 
 comonomers is permitted\, and crystallization can occur across the entire 
 composition range. Isodimorphic copolymers are characterized by a pseudo-e
 utectic point when the melting point is charted as a function of compositi
 on. A crystal structure typical of PA forms to the left of this point\, wh
 ile a PB-type crystal structure is found to the right. The presence of thi
 s pseudo-eutectic point means that the melting temperature can be adjusted
  by the copolymer composition\, as well as their crystallinity\, crystal s
 tructure\, and mechanical properties. Recently\, we reported a new crystal
 lization mode that combines isomorphic and isodimorphic behavior in alipha
 tic copolycarbonates. This versatility makes isodimorphic copolymers ideal
  materials for various applications\, including biodegradable films (for c
 opolyesters)\, thermoplastic elastomers\, hot-melt adhesives\, and tough s
 emi-crystalline polymers. This seminar will explore the effects of chemica
 l structure\, molecular weight\, and composition on the structure\, morpho
 logy\, nucleation\, and crystallization of a wide range of biodegradable i
 sodimorphic copolyesters and copolycarbonates.\n\n&nbsp\;\n\nAbout the Spe
 aker:\n\nProfessor Alejandro J. Müller is an IKERBASQUE Research Professo
 r at POLYMAT and the Department of Polymers and Advanced Materials: Physic
 s\, Chemistry\, and Technology within the Faculty of Chemistry at the Univ
 ersity of the Basque Country UPV/EHU in Donostia-San Sebastián\, Spain. H
 e has co-authored more than 550 publications in indexed journals\, which h
 ave attracted over 22\,000 citations\, giving him an h-index of 77. He has
  supervised 37 doctoral theses\, 62 Master\\'s theses\, and 96 undergradua
 te theses. Prof. Müller has delivered over 110 keynote\, plenary\, and in
 vited lectures across around 30 countries. He leads the Polymer Physics an
 d Advanced Manufacturing research area of POLYMAT (https://www.polymat.eu/
 en/research/Polymer-Physics-Advanced-Manufacturing) and coordinates the Po
 lymer Physics of Advanced Multiphasic Materials group. His research intere
 sts include the structure\, morphology\, nucleation\, crystallization\, an
 d crystallization kinetics of semicrystalline polymers and multiphase mate
 rials\, particularly polymer blends\, block copolymers\, biopolymers\, and
  nanocomposites. Prof. Müller has received several awards\, including the
  international Paul J. Flory Polymer Research Prize. He is a Corresponding
  Member of the National Academy of Engineering and Habitat of Venezuela (A
 NIH). In 2021\, he was elected as a corresponding member of the Latin Amer
 ican Academy of Sciences (ACAL). In July 2023\, the municipality of Beijin
 g\, China\, awarded him the \"Zhongguancun Award for International Coopera
 tion 2022\" for his scientific collaboration with the Institute of Chemist
 ry of the Chinese Academy of Sciences (ICCAS). He is an editor of the jour
 nal POLYMER (Elsevier)\, focusing on the joint areas of Polymer Physics an
 d Physical Chemistry 4:00 pm
END:VEVENT
END:VCALENDAR
