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SUMMARY:Leveraging Hydroxylamines For Iron-Catalyzed Nitrogen-Nitrogen Bond
  Formation
LOCATION:Chemistry A101
TZID:America/Denver
DTSTART:20250505T160000
UID:2026-04-28-20-18-50@natsci.colostate.edu
DTSTAMP:20260428T201850
Description:About the Seminar:\n\nThough nitrogen-nitrogen bonds are widely
  present in bioactive compounds and drug molecules\, they are difficult to
  construct due to the inherent nucleophilicity of both nitrogen atoms. Co
 nsequently\, nitrogen-nitrogen (N−N) bonds are typically integrated via 
 two C−N bond formations. Incorporation of the N−N bond is limited to c
 ommercially available hydrazine synthons and remains the most frequently u
 sed method in synthesizing N−N bond-containing molecules.  Direct N−N
  bond construction remains a highly efficient but underutilized method for
  synthesizing N−N bond-containing molecules.  I propose forming N–N b
 onds by reacting iron-derived nitrenes with amines. This approach operate
 s via a hydroxylamine precursor for iron-nitrene formation that is amenabl
 e to established iron-catalyzed methods 4:00 pm
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