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SUMMARY:Direct Sulfinamide and Sulfinamidine Synthesis via Metal Catalyzed 
 C–H Functionalization
LOCATION:Chemistry A101
TZID:America/Denver
DTSTART:20240617T160000
UID:2026-04-27-16-08-09@natsci.colostate.edu
DTSTAMP:20260427T160809
Description:Abstract:\n\nCompounds containing sulfinamide and sulfinamidine
  (i.e. sulfinamid(in)e) motifs are burgeoning within drug discovery due to
  their unique biological properties. These motifs are also useful synthons
  toward accessing valuable sulfur(VI) derivatives such as sulfonamides\, s
 ulfonimidamides\, and sulfondiimidamides. The most practiced routes to sul
 finamid(in)es engage sulfinylamine and sulfurdiimide reagents with prefunc
 tionalized starting materials such as organometallic reagents\, boroxines\
 , and carboxylic acids. However\, the most idyllic route to install sulfin
 amid(in)e functionality would be to directly couple C–H bonds with sulfi
 nylamine and sulfurdiimide reagents. To this end\, I propose a research pr
 ogram centered around leveraging a transition metal catalyzed C–H insert
 ion approach to allow for direct access to sulfinamid(in)e functionality. 
 This protocol would provide the first direct approach to sulfinamide(in)es
  and\, owing to synthetic versatility of these motifs\, provide access to 
 important sulfur(VI) derivatives. 4:00 pm
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