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SUMMARY:Closo-Boranes: Unique Structural Elements For Functional Materials
LOCATION:Chemistry A101
TZID:America/Denver
DTSTART:20241011T160000
UID:2026-04-22-07-10-18@natsci.colostate.edu
DTSTAMP:20260422T071018
Description:About the Seminar:\n\nCloso-Boranes are inorganic 3-D sigma aro
 matic compounds with steric and electronic properties attractive for desig
 ning multifunctional materials. Earlier work demonstrated that 10- and 12-
 vertex p-carboranes are suitable building blocks for liquid crystals. Anio
 nic closo-carbaborates have been used to design highly polar materials for
  LCD applications and ionic self-organizing electrolytes for battery appli
 cations. The high-lying HOMO of the decaborate dianion [closo-B10H10]2- ha
 s been exploited in the design of materials exhibiting photo-induced intra
 - and inter-molecular charge transfer processes. The synthesis of these ne
 w materials has required the development of new functionalization methods.
  For example\, phenyliodination activates B-H bonds towards highly regiose
 lective nucleophilic substitution.\n\n&nbsp\;\n\nAbout the Speaker:\n\nPio
 tr Kaszynski is a Professor of Chemistry at the Centre of Molecular and Ma
 cromolecular Studies of Polish Academy of Sciences and University of Łód
 ź in Poland. He received his M.Sc. degree from Warsaw Polytechnic in Pola
 nd in 1985\, Ph.D. degree in Organic Chemistry in 1991 (University of Texa
 s at Austin)\, and habilitation in 2007 (University of Łódź). He spent 
 two years at Caltech as a postdoctoral fellow working in the area of organ
 ic magnetic materials\, before joining Vanderbilt University in Nashville\
 , TN\, USA in 1993. In 2015 he moved the bulk of his research program to P
 olish Academy of Sciences\, while maintaining ties with Middle Tennessee S
 tate University in USA. His research involves boron clusters and stable ra
 dicals and is focused on the design\, synthesis and characterization of or
 ganic materials for electrooptical\, molecular electronics\, photovoltaic 
 and spintronic applications and for studying of molecular magnetism in sol
 id-state and liquid crystalline media. He has published over 200 original 
 papers\, and several book chapters and reviews. 4:00 pm
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