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SUMMARY:New Chemistry of Metal-Metal Bonded Compounds: Toward a Nitrogen En
 ergy Economy
LOCATION:Chemistry A101
TZID:America/Denver
DTSTART:20190001T000000
UID:2026-04-29-03-50-14@natsci.colostate.edu
DTSTAMP:20260429T035014
Description:About the Seminar:\n\nAmmonia has arisen as an attractive poten
 tial large-scale energy carrier due to its improved storage and transport 
 over hydrogen\, provoking calls to explore a potential Nitrogen Economy. T
 wo fundamental technologies are needed in order to realize a zero-carbon n
 itrogen energy economy: (1) Ammonia synthesis from solar electricity\, and
  (2) high-performance direct ammonia fuel cells. Both are mechanistically 
 challenging multi-proton\, multi-electron transformations\, prompting inve
 stigations into the fundamental coordination chemistry and reactivity of a
 mmonia with transition metals. We report unusual reactivity of ammonia wit
 h metal-metal bonded compounds that results in the spontaneous metal-cente
 red reduction and oxidation of ammonia to dinitrogen. Mechanistic aspects 
 of this chemistry will be presented as well as results on electrocatalytic
  oxidation of ammonia to dinitrogen.\n\n\n\n&nbsp\;\n\nAbout the Speaker:\
 n\nJohn was born in Atlanta\, GA and grew up in Newport News\, VA. He atte
 nded Virginia Tech from 1996 – 2000 where he obtained two degrees: a BA 
 in music theory and composition\, and a BS in chemistry. John then pursued
  graduate education in chemistry\, attending Texas A&amp\;M University fro
 m 2000 – 2004 where he worked as an NSF Graduate Research Fellow in the 
 research group of Prof. F. Albert Cotton. His graduate work involved synth
 etic and experimental studies to elucidate the electronic structure and me
 tal-metal bonding in linear trinuclear molecules that serve as models for 
 molecular wires. John then did postdoctoral work in Germany on a fellowshi
 p from the Alexander von Humboldt Foundation. From 2004 – 2006\, he work
 ed with Prof. Karl Wieghardt at the Max Planck Institute for Bioinorganic 
 Chemistry in Mülheim an der Ruhr\, Germany\, on new electrochemical and p
 hotochemical routes to unstable high-valent iron intermediates. In 2006\, 
 John joined the Department of Chemistry at the University of Wisconsin –
  Madison\, where he has established a vibrant research program tackling fu
 ndamental problems in coordination chemistry and bonding. His research inv
 olves what he describes as “non-classical” coordination chemistry\, th
 e chemistry of compounds that include metal-ligand and/or metal-metal mult
 iple bonding. He was promoted to Associate Professor in 2012\, full Profes
 sor in 2015\, and in 2016 John was appointed the Lester R. McNall Professo
 r of Chemistry. John’s honors include the Enrst Haage Prize (first recip
 ient\, 2006)\, an NSF CAREER Award (2008)\, an Alexander von Humbold alumn
 i fellowship (2015)\, the Vilas Faculty Mid-Career Investigator Award (201
 6)\, the H. I. Romnes Faculty Fellowship (2017)\, and election as a Fellow
  of the American Association for the Advancement of Science (AAAS) (2018)\
 , along with two university housing awards for teaching. John is a member 
 of the American Chemical Society\, AAAS\, and is a Fellow of the Wisconsin
  Initiative for Science Literacy. He has served on the editorial board of 
 Inorganic Chemistry\, is currently editing a volume of Comprehensive Coord
 ination Chemistry III\, and is Deputy Editor in Chief for Comments on Inor
 ganic Chemistry.\n\nOutside of chemical research\, John enjoys writing mus
 ic\, focusing particularly on chamber music. He has had several pieces per
 formed\, including Dances for String Quartet (1998)\, Sonata for Piano (20
 00)\, Sonata for Violincello and Piano (2000)\, Sonata for Tuba and Piano 
 (2009)\, Sonata for Violin and Piano (2014)\, and Three Petrarchian Sonnet
 s (2019). John plays violin\, viola\, and piano. 4:00 pm
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