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SUMMARY:Dual-Site Catalyst Strategy for Polypropylene Thermoplastic Elastom
 ers
LOCATION:Chemistry A101
TZID:America/Denver
DTSTART:20192001T000000
UID:2026-04-27-02-33-29@natsci.colostate.edu
DTSTAMP:20260427T023329
Description:Research Seminar Abstract\n\nRoughly 300 million tons of plast
 ic enters the global economy each year. Each of these serve specific\, p
 roperty-based purposes in commodity materials. Most of these commercial pl
 astics are composed of more than one polymer\, adding complexity of pos
 t-consumer separation. Minimizing the material diversity in our economy i
 s crucial\, as recycling these multi-polymeric materials is costly and tim
 e inefficient when compared using landfills and incineration. One propose
 d solution is to employ homopolymer thermoplastic elastomers. These mater
 ials\, when synthesized by a dynamic metallocene catalyst system\, exhibit
  tunable thermal and mechanical properties and offer a viable solution to 
 excessive plastic waste feedstocks. Investigations into the synthesis of s
 tereoblock polypropylene thermoplastic elastomers have taken place over 6 
 decades\, leading to current investigations by the Rieger group. To synthe
 size high-melting\, elastic polypropylene and address the lack of stereoco
 ntrol in homopolymer stereoblock growth\, dynamic dual-site metallocene 
 catalysts are employed under manipulated reaction conditions. The mechanis
 tic interplays of interconverting chelate ring conformers\, polymer chain 
 migration\, and chain-end epimerization towards varying polypropylene isot
 actic pentad contents will be discussed.\n\n&nbsp\;\n\nMacromolecules 201
 8\, 51 (3)\, 914-929 4:00 pm
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