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SUMMARY:Building and Breaking Molecular Ladders  to Develop Functional Mate
 rials
LOCATION:Chemistry A101
TZID:America/Denver
DTSTART:20192001T000000
UID:2026-04-04-16-01-53@natsci.colostate.edu
DTSTAMP:20260404T160153
Description:About the Seminar:\n\nOur interest in utilizing and incorporati
 ng strained rings in ladder-shaped molecular structures led to the develop
 ment of unusual organic materials. We developed Catalytic Arene-Norbornene
  AnnuLation (CANAL) to synthesize rigid ladder polymers from readily avail
 able norbornenes and aryl bromides. Efficient CANAL polymerization produce
 d rigid ladder polymers with molecular weights up to 1 MDa\, contorted con
 formations\, and various functionalities. These ladder polymers exhibited 
 high microporosity (pore width &lt\; 1 nm) and surprisingly high thermal s
 tability up to 400 °C without detectable Tg. Membranes from these polymer
 s were fabricated for gas separation and understanding gas transport in gl
 assy polymers.\n\nIn the quest for synthetic materials that transduce mech
 anical stimulation to multifaceted signals in response to force\, we devel
 oped a unique family of insulating polyladderenes\, which rapidly unzip un
 der force into semiconducting polymers. The force-induced unzipping of mac
 romolecular ladders opens new avenues for smart materials that transform t
 heir intrinsic properties drastically under stress and mechanistic underst
 anding of mechanotransduction in polymers.\n\n&nbsp\;\n\nAbout the Speaker
 :\n\nYan Xia received his undergraduate degree from Peking University (\\'
 02) and MSc from McMaster University (\\'05). He then obtained his PhD in 
 Chemistry from Caltech in 2010\, working on cyclic and bottlebrush polymer
 s under the guidance of Profs. Robert Grubbs and Julie Kornfield. Followin
 g his PhD\, he worked as a senior chemist at Dow Chemical for one and a ha
 lf years and then a postdoc associate with Prof. Brad Olsen at MIT Chemica
 l Engineering. He joined the chemistry faculty at Stanford in the summer o
 f 2013. His research interest lies in the design\, synthesis\, and manipul
 ation of organic materials and polymers\, driven by new synthetic capabili
 ty\, rational molecular design\, and curiosity. He is a recipient of Terma
 n Fellowship\, ARO Young Investigator Award\, 3M Non-Tenured Faculty Award
 \, NSF CAREER Award\, Thieme Chemistry Journals Award\, and Cottrell Scho
 lar Award. 4:00 pm
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